Nagoya University-led team of physicists use a synchrotron radiation X-ray source to probe a so-called "structure-less" transition and develop a new understanding of molecular conductors.

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Abstract: An initiator comprises: a first explosive substance, wherein the first explosive substance comprises a secondary explosive, and wherein at least the first explosive substance is capable of being initiated. The initiator comprises effectively no primary explosive. The secondary explosive can be a thermally-stable secondary explosive. A method of using an initiator comprises: initiating the initiator.

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The x-ray structure of HC8 reveals that two conformers of HC8 are present in the solid state: one elongated stretching to their maximum theoretical length, 19.8 Å, and one contracted at 19.1 Å presenting two gauche conformations (Fig. 1, A to C, and fig. S1). The crystal packing of chiral R-HC8 (Fig. 1B) or S-HC8 (Fig. 1C) reveals compact bent conformations with the heptyl chains orthogonally disposed to the urea moieties. The homomonomeric H-bonding association of the urea-urea planar ribbons of the neighboring ureas lie in the same plane with respect to one another, as previously observed (15). The NH—O=C– H-bond (dO—H of 1.90 Å) distances are the same along the ribbon and are consistent with other urea systems (15–18). Accordingly, continuous asymmetric layers of HC8 and R-HC8 or S-HC8 are generated in the solid state, such that the imidazole moieties are positioned at one end of each ribbon and strong hydrophobic van der Waals interactions between the alkyl chains stabilize the ribbon-like superstructures on the opposite side.

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