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He makes her laugh: Billy Crystal wore a suit with sneakers while at the even with his wife Janice (L) and Caroline Rhea looked great in red while taking daughter Ava Rhea Economopoulos (R) to the premiere

To further confirm the TDR results, we investigated the electronic structure of MGT using density functional theory (DFT) calculation by examining a new electronic state, which was constructed in the interface. As illustrated in fig. S4F, we calculated both CuPc and MGT as a system to obtain the CT process, instead of isolated molecules. We investigated the coupling of CuPc and MGT as well as the consequent CT at equilibrium using DFT calculations. The DFT results (Fig. 4I) showed that much more obvious electron transfer occurred from MGT to CuPc than from MG to CuPc, which gave theoretical evidence for the efficient CT between MGT and CuPc molecules. Moreover, to further elucidate the CT process, we determined the Fermi level, the conductive band (CB) and valence band (VB) of MGT, and the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) levels of different organic molecules using DFT calculation, which are shown in Fig. 4J. The Fermi level of GO was −4.6 eV from the vacuum level, while the HOMO and the LUMO levels of organic molecules were −7.9 and −3.4 eV for CC, −6.8 and −4.7 eV for PTCDA, −6.0 and −4.1 eV for CV, and −5.2 and −3.07 eV for CuPc, respectively. In general, Raman enhancement effect is derived from a robust CT between the substrate and the molecules (6). In the CuPc-MG system, the energy barrier from the Fermi level of GO to LUMO of CuPc is 1.53 eV. With the introduction of TiO2 to the MG system, charge redistribution occurs around the interface between TiO2 and molecules, which leads to the alignment of the energy levels between TiO2 and GO. In this case, the narrow energy barrier is 0.9 eV from the Fermi level of GO to CB of TiO2 and 0.83 eV from CB of TiO2 to LUMO of CuPc, respectively, which are much smaller than that in the MG system. Thus, compared with the CuPc-MG system, CT occurs much easier, and more obvious CT selective enhancement was observed in the SERS spectra of the MGT-CuPc system. Different from CuPc, the LUMO levels of CV (−4.10 eV) and PTCDA (−4.70 eV) were lower than CB of TiO2 (−3.70 eV; Fig. 4J), which results in a rare contribution to CT between the molecules and MGT with the introduction of TiO2, preventing a further enhancement of Raman intensity. The results of theoretical calculation also showed that there was an efficient CT between the molecules and the substrate, leading to SERS enhancement with a high EF value, which agrees well with that proposed by TDR measurement above.

Your first gray hair is a rite of passage, a reminder that you’re getting older, wiser, and that you are blessed to be a vibrant human being. Like laugh lines, gray hairs are a totem of a life well lived. But of course, most of us can’t help but wonder: Why do we go gray, and what, if anything, do we do about it — or not? Here’s everything you ever wanted to know about being a silver fox or dyeing your salt-and-pepper strands.

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Inventor(s): Abdelaziz Rahy (Waxahachie, TX), Raynard Rene Veldman (Mansfield, TX) Assignee(s): Magnablend, Inc. (Waxahachie, TX) Law Firm: Brinks Gilson Lione (7 non-local offices) Application No., Date, Speed: 15110545 on 01/07/2015 (1434 days app to issue)

The film, currently in post-production, has an ensemble cast featuring Daniel Mays (Atonement), Tuppence Middleton (The Imitation Game), James Purefoy (Solomon Kane), David Hayman (Finding Your Feet), Dave Johns (I, Daniel Blake) Sam Swainsbury (Thor: The Dark World), Maggie Steed (Paddington 2) Christian Brassington (St Trinian’s 2) and Noel Clarke (Brotherhood). Here’s a first look at some of the team.