The Concord Singers will perform at the Best Western Plus at 2 p.m. Josh Norman German music follows at 3:15 p.m. The Concord Singers are back on stage at 6:45 p.m. followed by The Bockfest Boys at 8:30 pm.
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Samples for SFG experiments were formed on 10-mm CaF2 equilateral prisms coated with a layer of SiO2 (~100 nm) (44). Half of the prism face was also coated with 150-nm Au for use as a reference. To form the bilayers, 25 μl of vesicle solution was added to 1 ml of aqueous 0.1 M PBS solution containing 0.2 M NaCl. A flow cell was formed by the CaF2 prism, Teflon O-ring, and Teflon backplate with Teflon tubes as input and output ports connected to two syringes. The vesicle PBS mixture was added to one syringe and manually passed back and forth between syringes across the CaF2 surface. The solution was then stationary for about 10 min to completely form the bilayer. After, excess PBS solution was used to rinse off any remaining vesicles. The laser system used for the SFG experiments was a Ti-sapphire amplifier (Coherent Legend Elite Duo) that was seeded by a Ti-sapphire oscillator (Coherent Micra-5) and provided 5 mJ, 25-fs duration, and 800-nm pulses at a repetition rate of 1 kHz (45). One portion of the output is spectrally narrowed with a Fabry-Perot etalon (TecOptics Inc.) to form the “visible” upconversion beam, whereas another portion is used to generate tunable broadband infrared pulses in a commercial optical parametric amplifier (Coherent OPerA Solo). The visible beam [10 μJ; 792.8 nm; FWHM (full width at half maximum), 10 cm−1] and infrared beam (18 μJ; center frequencies of 3070, 3230, and 3670 cm−1; FWHM, ~300 cm−1) were focused onto the prism-liquid interface at 60° and 65°, respectively, with respect to the surface normal. The 2550- to 4000-cm−1 frequency range was covered by setting the OPerA at three central positions. The SFG field was generated in reflection, dispersed on a diffraction grating, and imaged onto a liquid nitrogen–cooled charge-coupled device (Princeton Instruments). The polarization of the individual beams was controlled with the combination of a waveplate and polarizer. All data were normalized to the nonresonant Au signal obtained in ppp-polarization combination collected immediately before vertically translating the flow cell to the sample. In addition to the SFG polarization combinations shown in the main text, we also measured the interference polarization combinations (+45)pp, (−45)pp, (+45)sp, and (−45)sp, where the measured SFG polarization was set to +45° or −45°. The interference combinations mix achiral and chiral signals, measuring the norm square of or , respectively, where χ is the second-order nonlinear susceptibility. The difference between the +45° and −45° polarization combinations is thus illustrative of a chiral response. The ±45° polarizations were measured simultaneously, providing a robust chiral detection method immune to laser fluctuations, as described by McDermott et al. (38). The interference method typically has better fidelity in detecting chirality but can be harder to interpret because of the unknown complex phase of the interference. Figure S6 shows the differences in the +45° and −45° polarizations. As expected, the interference chiral response showed clear chiral signals with a higher signal-to-noise ratio than the pure chiral measurement. The interference spectra show the same features in both the NH and OH frequency ranges, as the pure achiral and chiral responses, but are more complicated to analyze because of the interference. These data provide further proof that both the channels themselves and the channel water structures are chiral. Figure S7 shows the FTIR attenuated total reflection (ATR) spectrum of dry HC8 powder. A band around 2800 cm−1 due to the imidazole was observed, confirming this assignment in the SFG spectra.
A born competitor, O’Leary twice raced in the Irish Admiral’s Cup team. In 1975, when his rugby playing days were long over, he qualified in the team trial series in company with two other famous Cork skippers, Clayton Love and Denis Doyle, That the national team consisted of three Cork boats rankled a bit with sailors from within the Pale at the time.
– From Joe Pinsker’s conversation with communications scholar Jason Farman in The Atlantic. To read the piece, please hit this link:
Sister Antone was born in Central Falls, and educated at Salve Regina University, Villanova University, Harvard University and MIT Sloan School of Management.
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Coxe has now headed three of the most most important preservation organizations in New England. As the long-time Executive Director of Save the Bay in the 1980′s and 1990′s, she was a powerful force in driving the preservation of Rhode Island’s open space and improvements to Narragansett Bay.
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In complex GPU-bound tests, such as a walk around the bustling Diamond City, we also see a divide in performance between the two consoles. Though most locations hold mostly steady at 30fps, this is one of the more densely packed, detailed spots in the game in terms of overall NPC count and geometry layout. As a result, both PS4 and Xbox One are prone to drops when walking around its centre, and Sony’s machine consistently gives us the smoother return. On overlooking the city as a whole, Xbox One lags behind at a sustained 25fps in this case, while PS4 delivers at 28fps until we leave the scene. There’s no question in this sense that PS4 leverages its raw hardware advantage into a performance lead – despite resolutions and assets being identical with Microsoft’s platform.
Survivors include a son, Jackie (Jenny) Williams, Twin City; daughter, Joyce (Billy) Edwards, Aragon; daughter, Robbie Brown, Rome; granddaughter, Amanda (Bruno) Arroyo, Rome; grandsons: Josh (Marissa) Edwards, Aragon, Brandly (Amber) Brown, Aragon, Brandon Williams, Twin City, and Tyler Williams, Hot Springs, Ark.; great granddaughters: Shelby Williams, Ava Edwards, Layla Edwards and Adaley Brown; great grandsons: Otis Williams and Oliver Williams, brother, Donald Williams and a number of nieces and nephews also survive.
Abstract: An edible piata system may have an edible piata including edible upper and lower shells, a hanging rod for attaching the edible piata to a hanging assembly, a support plate for supporting the edible piata and edible contents, and the hanging assembly for supporting the edible piata, hanging rod, and support plate to suspend the edible piata for consumption. The edible piata system may be made by a method for producing an edible piata.
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