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“Despite this crazy state, it’s possible for a Rhode Island woman to reach this self-made list. For that I am proud,” said Rafaelian, Founder and CEO of Alex and Ani in an interview with GoLocal.

Surface-enhanced Raman scattering (SERS) has been a promising analytical technique for the detection of trace species because of its remarkable advantages, namely, it is sensitive, it is nondestructive, it has a quick response time, and it provides unique information on the species (1–3). Studies on noble metal nanostructures, such as Au, Ag, and Cu, indicate that the tremendous electromagnetic field enhancement at the hotspots greatly increases the sensitivity of SERS (4). However, the SERS effect based on electromagnetic field enhancement has no selectivity for Raman reporters, resulting in complicated signal outputs generated by unexpected interactions (5). Recently, another mechanism, chemical enhancement mechanism (CM), which is related to the formation of charge transfer (CT) states between the adsorbed molecules and the nanoparticles (NPs) (6), has attracted more attention. Compared with SERS, which is based on electromagnetic field mechanism, this unique method always demonstrates high molecule selectivity. Most substrates based on CM show stable and reproducible SERS signals without agglomeration, which is different from those obtained from noble metals. Moreover, the CM-based substrate exhibits good biocompatibility without cytotoxic outcomes. Thus, various new materials have been developed to investigate CT in plasma-free SERS, such as graphite oxide (GO) and semiconductor materials (7). However, only 10 to 100 enhancements have been achieved by these materials (8, 9), limiting their potential applications for reliable quantitative detection in biological and biomedical analysis and diagnosis. Accordingly, low enhancement factor (EF) values prevent further applications of CM-based SERS substrates.

(A) SEM image of the MG substrate. (B) TEM image of the MG substrate. Inset: Size distribution of MG by dynamic light scattering measurement. a.u., arbitrary units. (C) SEM image of MGT nanocomposites. (D) TEM image of MGT nanocomposites. Inset: Size distribution of MGT by dynamic light scattering measurement. (E) N2 sorption isotherms and (F) corresponding pore size distribution curves of the MGT. (G) (I) Bright-field EDS images, (II) high-magnification image of (I) (marked with a green square), (III) high-resolution image of a select region in (II) (marked with a red square), and (IV to VIII) low-/high-magnification EDS images of MGT. (H) XRD patterns of (I) Fe3O4 NPs, (II) MG, (III) MGT, and (IV to VI) standard patterns of (IV) Fe3O4, (V) GO, and (VI) porous TiO2 NPs. (I) Raman spectra and (J) FTIR spectra of (I) Fe3O4 NPs, (II) GO, (III) MG, (IV) Fe3O4@TiO2 (MT), and (V) MGT. (K) The magnetic hysteresis loops at 300 K of the MGT. Inset: Photograph of the magnetic separation process of the MGT from the solution. emu, electromagnetic units.

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“The strong U.S. economy should benefit all of us,” he added. “We’re looking forward to a prosperous 2019 for us and for the entire plastics industry.”

Ben Tré is a world leader in innovating cast glass as a sculptural medium, and his work has been exhibited at more than 100 museum and public collections worldwide — and his studio is located in Pawtucket, RI. 

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The most common stain removers are surfactants. Examples include dish soap, laundry detergent, and many industrial suds. Surfactant molecules have two polar ends, one hydrophilic (or water-friendly) and one hydrophobic. These cleaners work a bit like velcro: One end attaches to a water molecule, one end attaches to a molecule of the stain, and off they swirl. However, the same reaction allows surfactants to remove dyes as well as stains from your clothes, so read the label before using this type of stain remover.

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Short supplies of nylon 6/6 resin topped the list of concerns. The material is used in many auto parts but was in short supply because of reduced availability of adiponitrile feedstock.